A specimen of nickel powder is studied by X—ray di

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A specimen of nickel powder is studied by X—ray diffractometry.The sample is irradiated with Cr Kα radiation,which has a wavelength,λ,of 2.29
.Only three diffraction peaks are observed in total:(111),(200),and(220).Explain why reflections from planes of higher Miller index are not observed. The lattice constant,a,for nickel is 3.53

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题库:大学本科,理学,物理学类

标签:正确答案,请帮忙,radiation

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2024-10-29 19:36:12

正确答案:Ni is FCCso the next plane in the sequence of reflections is(311).Let’s use Bragg’s Lawλ=2dhklsinθ to determine the angle of reflection for(311). d311=a/ λ=2hklsinθ θ=sin-1(λ/2dhkl)=sin-1(1.08)=undefined Thusthe only way to measure reflections from planes of higher Miller index than(220)is to change the target in the X-ray generator to a heavier element in order to decrease the wavelength of the radiation.In this wayit is possible to satisfy Bragg’s Law.
NiisFCC,sothenextplaneinthesequenceofreflectionsis(311).Let’suseBragg’sLaw,λ=2dhklsinθtodeterminetheangleofreflectionfor(311).d311=a/λ=2hklsinθθ=sin-1(λ/2dhkl)=sin-1(1.08)=undefinedThus,theonlywaytomeasurereflectionsfromplanesofhigherMillerindexthan(220)istochangethetargetintheX-raygeneratortoaheavierelementinordertodecreasethewavelengthoftheradiation.Inthisway,itispossibletosatisfyBragg’sLaw.

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