A specimen of nickel powder is studied by X—ray di
A specimen of nickel powder is studied by X—ray diffractometry.The sample is irradiated with Cr Kα radiation,which has a wavelength,λ,of 2.29.Only three diffraction peaks are observed in total:(111),(200),and(220).Explain why reflections from planes of higher Miller index are not observed. The lattice constant,a,for nickel is 3.53
.
请帮忙给出正确答案和分析,谢谢!
参考解答
正确答案:Ni is FCCso the next plane in the sequence of reflections is(311).Let’s use Bragg’s Lawλ=2dhklsinθ to determine the angle of reflection for(311). d311=a/ λ=2hklsinθ θ=sin-1(λ/2dhkl)=sin-1(1.08)=undefined Thusthe only way to measure reflections from planes of higher Miller index than(220)is to change the target in the X-ray generator to a heavier element in order to decrease the wavelength of the radiation.In this wayit is possible to satisfy Bragg’s Law.
NiisFCC,sothenextplaneinthesequenceofreflectionsis(311).Let’suseBragg’sLaw,λ=2dhklsinθtodeterminetheangleofreflectionfor(311).d311=a/λ=2hklsinθθ=sin-1(λ/2dhkl)=sin-1(1.08)=undefinedThus,theonlywaytomeasurereflectionsfromplanesofhigherMillerindexthan(220)istochangethetargetintheX-raygeneratortoaheavierelementinordertodecreasethewavelengthoftheradiation.Inthisway,itispossibletosatisfyBragg’sLaw.
相似问题
_______是非细胞形态的生命体 是迄今发现的最小 最简单的有机体。请帮忙给出正确答案和分析 谢谢
_______是非细胞形态的生命体,是迄今发现的最小、最简单的有机体。请帮忙给出正确答案和分析,谢谢!
NaCl晶体的衍射指针h k l全奇时 衍射强度较弱;全偶时 衍射强度较强 试证明之。请帮忙给出正确
NaCl晶体的衍射指针h、k、l全奇时,衍射强度较弱;全偶时,衍射强度较强,试证明之。请帮忙给出正确答案和分析,谢谢!
在90%乙醇水溶液的质子共振谱中 —OH —CH2— —CH3中质子所产生的三组峰中的小峰数分别为(
在90%乙醇水溶液的质子共振谱中,—OH、—CH2—、—CH3中质子所产生的三组峰中的小峰数分别为( )。A.1、3、4B.3、8、3C.3、3、8D.1、4、3请帮忙给
某种AχBy盐结晶成立方晶体 晶胞中A原子在每个顶点和处 B原子在位置。①作图画出A B原子的位置;
某种AχBy盐结晶成立方晶体,晶胞中A原子在每个顶点和处,B原子在位置。①作图画出A、B原子的位置;②求AχBy晶胞中χ和y的数值;③若晶胞的边长为600pm
为什么14种空间点阵型式中有正交底心 而无四方底心 也没有立方底心型式?请帮忙给出正确答案和分析 谢
为什么14种空间点阵型式中有正交底心,而无四方底心,也没有立方底心型式?请帮忙给出正确答案和分析,谢谢!
