Cyano complexes of transition metal ions such as F
Cyano complexes of transition metal ions such as Fe2+ and Cu2+ are often yellow in color while aquo complexes are often green or blue.How to explain this difference in color?
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参考解答
正确答案:CN is a strong-field ligandwhich causes a greater energy separation of the two group of d electrons than H2O does.Promotion of an electron from a lower to a higher d level can result from the absorption of the appropriate component of white lightso the transmitted light is colored.For the energy difference produced by H2O is smaller than that by cyanothe color we observed changes from yellow tO green or blue.
CNisastrong-fieldligand,whichcausesagreaterenergyseparationofthetwogroupofdelectronsthanH2Odoes.Promotionofanelectronfromalowertoahigherdlevelcanresultfromtheabsorptionoftheappropriatecomponentofwhitelight,sothetransmittedlightiscolored.FortheenergydifferenceproducedbyH2Oissmallerthanthatbycyano,thecolorweobservedchangesfromyellowtOgreenorblue.
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